Model for the impedance analysis in a three electrode solid state electrochemical cell
Identifieur interne : 000F29 ( Main/Exploration ); précédent : 000F28; suivant : 000F30Model for the impedance analysis in a three electrode solid state electrochemical cell
Auteurs : G. E. Lagos [Royaume-Uni] ; N. Bonanos [Royaume-Uni] ; B. C. H. Steele [Royaume-Uni]Source :
- Electrochimica Acta [ 0013-4686 ] ; 1982.
Abstract
A T-network model for the determination of the electrode impedances in a three electrode solid state electrochemical cell is postulated and discussed. The model is applied to a Li solid battery where the electrolyte is the polymer (PEO)8LiCF3SO3 and the positive electrode is the insertion electrode V6O13 + x. The Li metal reference electrode is found to have an impedance considerably greater than that of the working (V6O13 + x) or the counter electrode (Li). The significance of these impedances is discussed in relation to the geometry and construction of solid electrolyte cells, and to their suitability for potentiostatic measurements.
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DOI: 10.1016/0013-4686(83)85219-0
Affiliations:
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<front><div type="abstract" xml:lang="en">A T-network model for the determination of the electrode impedances in a three electrode solid state electrochemical cell is postulated and discussed. The model is applied to a Li solid battery where the electrolyte is the polymer (PEO)8LiCF3SO3 and the positive electrode is the insertion electrode V6O13 + x. The Li metal reference electrode is found to have an impedance considerably greater than that of the working (V6O13 + x) or the counter electrode (Li). The significance of these impedances is discussed in relation to the geometry and construction of solid electrolyte cells, and to their suitability for potentiostatic measurements.</div>
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